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Reactions that allow complex molecular fragments to be combined in high yield occupy an exalted position in organic synthesis because they are fundamental to convergent synthesis strategi Recent discoveries from our laboratories show that bimolecular reactions of structurally elaborate tertiary carbon radicals and electron deficient alkenes can unite complex fragments by forming a new sp3 All sigma aldrich articles in Chemistry World Your subscription expires today If you do not renew today then from tomorrow you will only have limited access to premium content on our website and will no longer receive our print or digital magazine

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